Nucleophilic substitution in dibenz[<i>b</i>,<i>d</i>]iodolium and 11,12-dihydro-10H-dibenz[<i>b</i>,<i>g</i>]iodocinium cations

Authors

  • А. Н. Ванчиков M. V. Lomonosov Moscow State University, Moscow 119899
  • M. C. Бобылева M. V. Lomonosov Moscow State University, Moscow 119899
  • E. E. Комиссарова M. V. Lomonosov Moscow State University, Moscow 119899
  • H. C. Куликов M. V. Lomonosov Moscow State University, Moscow 119899
  • T. П. Толстая M. V. Lomonosov Moscow State University, Moscow 119899

Abstract

Treatment of dibenz[b,d]iodolium tetrafluoroborate with NO2−, Br−, and N3 ions gave, along with nucleophilic substitution products, 2-nitro-, 2-bromo-, and 2-azido-2′-iodiphenyls, diphenyl, 2-iododiphenyl, and 2,2′-diiododiphenyl (products of one electron reduction), whereas 11,12-dihydro-10H-dibenz[b,g]iodocinium tetrafluoroborate underwent nucleophilic substitution with all three nucleophiles to give a single product in each case: 1-(2-nitrophenyl)-, 1-(2-bromophenyl)-, or 1-(2-azidophenyl)-3-(2-iodophenyl)propane.

How to Cite
Vanchikov, A. N.; Bobyleva, M. S.; Komissarova, E. E.; Kulikov, N. S.; Tolstaya, T. P. Chem. Heterocycl. Compd. 1998, 34, 371. [Khim. Geterotsikl. Soedin. 1998, 34, 405.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF02290735

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Published

1998-03-25

Issue

No. 3 (1998)

Section

Original Papers