Porphyrins. 35. Unusual course of the Vilsmeirr reaction when formylating the platinum complex of octaethylporphyrin (revision of the known reaction)

Authors

  • Г. В. Пономарев Institute of Biomedicinal Chemistry, Russian Academy of Medical Sciences, Moscow 119832
  • Д. B. Яшyнский Institute of Biomedicinal Chemistry, Russian Academy of Medical Sciences, Moscow 119832
  • А. C. Московкин Institute of Biomedicinal Chemistry, Russian Academy of Medical Sciences, Moscow 119832

Abstract

The formation of complexes of β-formyl-heptaethylporphyrin and β-(2-formylvinyl)-heptaethylporphyrin in addition to the expected mesoformylporphyrin was detected when formylating the platinum complex of actaethylporphyrin by the Wilsmeier reaction. A possible mechanism is proposed for the unusual formation of similar compounds.

How to Cite
Ponomarev, G. V.; Yashunskii, D. V.; Moskovkin, A. S. Chem. Heterocycl. Compd. 1997, 33, 271. [Khim. Geterotsikl. Soedin. 1997, 324.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF02253105

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Published

2025-10-27

Issue

No. 3 (1997)

Section

Original Papers