Free radicals in the electrochemical reduction of derivatives of 3,5-dinitro-1,2-dihydropyridine

Authors

  • Я. Страдынь Latvian Institute of Organic Synthesis, Riga LV-1006
  • P. Гавар Latvian Institute of Organic Synthesis, Riga LV-1006
  • Л. Баумане Latvian Institute of Organic Synthesis, Riga LV-1006
  • Б. Виганте Latvian Institute of Organic Synthesis, Riga LV-1006
  • Г. Дубур Latvian Institute of Organic Synthesis, Riga LV-1006

Abstract

The characteristics (potentials, limiting currents, reversibility) of the electrochemical reduction of 3,5-dinitro-1,2-dihydropyridines were determined by cyclic voltammetry and polarography. It was established by ESR that the free radicals formed in these processes have a radical-dianion structure in the case of both the N-unsubstituted and the N-substituted dihydropyridines. The hyperfine coupling constants of the interaction between the unpaired electron and the nuclei of the atoms at various positions of the heterocycle were determined.

How to Cite
Stradyn', Ya.; Gavar, R.; Baumane, L.; Vigante, B.; Dubur, G. Chem. Heterocycl. Compd. 1997, 33, 184. [Khim. Geterotsikl. Soedin. 1997, 212.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF02256760

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Published

1997-02-25

Issue

No. 2 (1997)

Section

Original Papers