A NEW EXAMPLE OF LINEAR DISILOXANE: SYNTHESIS AND X-RAY CRYSTAL STRUCTURE OF BIS(2-SILOLYL)TETRAMETHYLDISILOXANE

Authors

  • Shigehiro Yamaguchi Institute for Chemical Research, Kyoto University, Uji, Kyoto 611
  • Ren-Zhi Jin Institute for Chemical Research, Kyoto University, Uji, Kyoto 611
  • Motoo Shiro Institute for Chemical Research, Kyoto University, Uji, Kyoto 611
  • Kohei Tamao Institute for Chemical Research, Kyoto University, Uji, Kyoto 611

Abstract

Bis(2-silоlyl)tetramethyldisilоxane has been obtained by an attempted Wurtz-type coupling of (2-silolyl)dimethylsilyl chloride using sodium metal and its linear Si—O—Si geometry has been demonstrated by X-ray crystallography.

How to Cite
Yamaguchi, S.; Jin, R.-Z.; Shiro, M.; Tamao, K. Chem. Heterocycl. Compd. 1997, 33, 1. [Khim. Geterotsikl. Soedin. 1997, 1.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF02256755

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Published

1997-02-25

Issue

No. 2 (1997)

Section

Original Papers