Cleavage of enantiomers of methano-1H-cyclooct[<i>b</i>]indol-9-ol and their absolute configuration

Abstract

Chiral [6R and 6S-(6α, 9α, 10α)]methano-1H-cyclooct[b]indol-9-ols were segregated into enantiomers through diastereomeric esters with (R)-α-trifluoromethylphenylacetic acid. The absolute configuration of the enantiomers was established by the NMR method using the shift reagent Eu(fod)₃ and the circular dichroism spectra.

How to Cite
Butkus, É.; Malinauskene, Y.; Kadzyauskas, P. Chem. Heterocycl. Compd. 1995, 31, 72. [Khim. Geterotsikl. Soedin. 1995, 82.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01171296