Synthesis and redox properties of pyrroledithiocarboxylic acid esters

Authors

  • Л. Н. Сoбeнина Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk
  • Л. E. Протасова Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk
  • М. П. Сергеева Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk
  • O. B. Петрова Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk
  • T. Н. Аксаментова Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk
  • O. Б. Козырева Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk
  • P. И. Половникова Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk
  • А. И. Михалева Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk
  • Б. А. Трофимов Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk

Abstract

Pyrrole-2-dithiocarboxylates were obtained by reacting alkylpyrroles with carbon disulfide in the presence of alkyl halides in the KOH-DMSO system. The pyrrole and its aryl derivatives were primarily converted into pyrrole-1-dithiocarboxylates in these conditions. The electronic structure and redox properties of the synthesized compounds were investigated by polarography and cyclic voltammetry.

How to Cite
Sobenina, L. N.; Protasova, L. E.; Sergeeva, M. P.; Petrova, O. V.; Aksamentova, T. N.; Kozyreva, O. B.; Polovnikova, R. I.; Mikhaleva, A. I.; 
Trofimov, B. A. Chem. Heterocycl. Compd. 1995, 31, 40. [Khim. Geterotsikl. Soedin. 1995, 47.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01171288

Published

1995-01-25

Issue

Section

Original Papers