Synthesis and structure of the betaine system of 2-hydrazino-3,4,6-trichloro-5-cyanopyridine and diazomethane

Authors

  • B. Г. Карцев Institute of Chemical Physics at Chernogolovka, Russian Academy of Sciences, Chernogolovka 142432
  • Э. М. Гизатуллина Institute of Chemical Physics at Chernogolovka, Russian Academy of Sciences, Chernogolovka 142432
  • 3. Г. Алиев Institute of Chemical Physics at Chernogolovka, Russian Academy of Sciences, Chernogolovka 142432
  • C. А. Талипов Institute of Chemical Physics at Chernogolovka, Russian Academy of Sciences, Chernogolovka 142432
  • А. С. Набатов Institute of Chemical Physics at Chernogolovka, Russian Academy of Sciences, Chernogolovka 142432

Abstract

Upon reaction of 2-hydrazino-3,4,6-trichloro-5-cyanopyridine with diazomethane, we obtain a betaine system, 1-trimethyl-2-(3,4,6-trichloro-5-cyanopyrid-2-yl)hydrazin-1-io-2-ide, the structure of which has been established by X-ray diffraction. We calculate the electronic structure of the betaine using the CNDO/3 method.

How to Cite
Kartsev, V. G.; Gizatullina, É. M.; Aliev, Z. G.; Talipov, S. A.; Nabatov, A. S. Chem. Heterocycl. Compd. 1994, 30, 444. [Khim. Geterotsikl. Soedin. 1994, 505.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01169939

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Published

1994-04-25

Issue

No. 4 (1994)

Section

Original Papers