REARRANGEMENT OF CYCLOPROPYLBORANE INTO BORETANE

Authors

  • М. Рубина Department of Chemistry, University of Kansas and Center for Environmentally Beneficial Catalysis
  • М. Рубин Department of Chemistry, University of Kansas and Center for Environmentally Beneficial Catalysis

DOI:

https://doi.org/10.1007/1203

Keywords:

boretane, cyclopropylborane, ConcIRT-spectra, 19F NMR spectroscopy, real time IR spectroscopy, ring expansion

Abstract

Previously unknown boron-containing four-membered unsaturated heterocycle boretane was obtained via novel thermal rearrangement of cyclopropylborane and investigated by NMR and IR spectroscopy. Formation of boretane was also confirmed through its chemical transformation into more stable derivatives.

Authors: M. Rubina and M. Rubin.

English Translation in Chemistry of Heterocyclic Compounds, 2012, 48 (5), pp 807-821

http://link.springer.com/article/10.1007/s10593-012-1060-9

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Published

2013-11-21

Issue

No. 5 (2012)

Section

Original Papers