PREPARATION OF FUSED <i>N</i>-PHENYL-SUBSTITUTED PYRIDINIUM DERIVATIVES BY DIRECT PHENYLATION WITH NUCLEOGENIC PHENYL CATIONS

Authors

  • Н. Е. Щепина Natural Science Institute, Perm State University
  • В. В. Аврорин St. Petersburg State University
  • Г. А. Бадун Moscow M. V. Lomonosov State University
  • С. Б. Льюис James Madison University
  • С. Е. Уханов Perm State Technical University

DOI:

https://doi.org/10.1007/1256

Keywords:

nucleogenic phenyl cations, N-phenylacridinium salts, N-phenylphenanthridinium salts, tritium, nuclear-chemical synthesis

Abstract

The direct phenylation of a nitrogen atom has been carried out for the first time in fused pyridine derivatives by ion-molecular interaction of nucleogenic phenyl cations with acridine and phenanthridine. N-Phenylacridinium and -phenanthridinium compounds, which are sensitive markers for biological investigations, were obtained labeled with tritium.

Authors: N. E. Shchepina, V. V. Avrorin, G. A. Badun, S. B. Lewis, and S. E. Ukhanov.

English translation in Chemistry of Heterocyclic Compounds, 2012, 48 (2), pp 301-308

http://link.springer.com/article/10.1007/s10593-012-0990-6

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Published

2013-11-27

Issue

No. 2 (2012)

Section

Original Papers