THE INTERACTION OF 1<i>H</i>-AZOLES WITH NITROSOCHLORIDES OF ADAMANTANE SERIES

Authors

  • П. Е. Красников Samara State Technical University
  • Е. А. Сиднин Samara State Technical University
  • В. А. Осянин Samara State Technical University
  • Ю. Н. Климочкин Samara State Technical University

DOI:

https://doi.org/10.1007/1701

Keywords:

alkylidene adamantanes, α-azolyl oximes, 1Н-azoles, nitrosoalkenes, nitrosochlorides, aza-Michael reaction

Abstract

The interaction of nitrosochlorides based on 2-alkylidene adamantanes and 1Н‑azoles in pyridine medium produced α-azolyl oximes of adamantane series. The reaction occurred as a conjugated 1,4‑addition to in situ generated nitrosoalkenes acting as Michael acceptors. The structure of phenyl-[2-(4-phenyl-1Н‑imidazol-1-yl)adamantan-2-yl]methanone (Е)-oxime was studied by X-ray crystallography.

How to Cite
Krasnikov, P. E.; Sidnin, E. A.; Osyanin, V. A.; Klimochkin, Yu. N. Chem. Heterocycl. Compd. 2014, 50, 1090. [Khim. Geterotsikl. Soedin. 2014, 1183.]

For this article in the English edition see DOI 10.1007/s10593-014-1568-2

Author Biographies

П. Е. Красников, Samara State Technical University

Павел Евгеньевич Красников

Е. А. Сиднин, Samara State Technical University

Евгений Анатольевич Сиднин

инженер кафедры органической химии

В. А. Осянин, Samara State Technical University

Виталий Александрович Осянин

Ю. Н. Климочкин, Samara State Technical University

Юрий Николаевич Климочкин

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Published

2014-09-01

Issue

No. 8 (2014)

Section

Original Papers