COPPER CHROMITE NANOPARTICLES AS AN EFFICIENT AND RECYCLABLE CATALYST FOR FACILE SYNTHESIS OF 4,4'-(ARYLMETHANEDIYL)BIS(3-METHYL-1<i>H</i>-PYRAZOL-5-OL) DERIVATIVES

Authors

  • Javad Safaei-Ghomi University of Kashan
  • Bahareh Khojastehbakht-Koopaei University of Kashan
  • Safura Zahedi University of Kashan

DOI:

https://doi.org/10.1007/1926

Keywords:

4, 4'-(arylmethanediyl)bis(3-methyl-1H-pyrazol-5-ols), copper chromite, ethyl acetoacetate, nanoparticles, aqueous media

Abstract

In this study, pure spinel nanoparticles of copper chromite (CuCr2O4) were synthesized by coprecipitation method. These nanoparticles were characterized by X-ray diffraction, scanning electron microscopy, and FTIR. CuCr2O4 nanoparticles were found to be an efficient catalyst for the synthesis of  4,4'-(arylmethanediyl)bis(3-methyl-1H-pyrazol-5-ols) via pseudo-five-component reaction of aldehydes, hydrazine hydrate, and ethyl acetoacetate. The present methodology offers several advantages such as excellent yields, simple procedure, and mild conditions. The catalyst can be reused at least five times without any obvious change in its catalytic activity.

How to Cite
Safaei-Ghomi, J.; Khojastehbakht-Koopaei, B.; Zahedi, S. Chem. Heterocycl. Compd. 2015, 51, 34. [Khim. Geterotsikl. Soedin. 2015, 51, 34.]

For this article in the English edition see DOI 10.1007/s10593-015-1656-y

Published

2015-01-22

Issue

Section

Original Papers