SYNTHESIS AND STRUCTURE OF DI(2-PHENYL-8-QUINOLYL) DISELENIDE AND ZINC BIS[(2-PHENYL-8-QUINOLYL)SELENOLATE]

Authors

  • Э. Силинь Institute of Inorganic Chemistry, Riga Technological University
  • С. Беляков Latvian Institute of Organic Synthesis
  • Я. Ашакс Institute of Inorganic Chemistry, Riga Technological University
  • А. Токмаков Latvian Institute of Organic Synthesis, Institute of Solid State Physics, Latvian University
  • Л. Печ Institute of Inorganic Chemistry, Riga Technological University
  • Д. Зарума Institute of Inorganic Chemistry, Riga Technological University

DOI:

https://doi.org/10.1007/2100

Keywords:

intracomplex compounds of (2-phenyl-8-quinolyl)selenolates, di(2-phenyl-8-quinolyl)diselenide, zinc complexes, molecular and crystal structure

Abstract

Di(2-phenyl-8-quinolyl) diselenide [2-(C6H5)C9H5NSe]2 and zinc bis[(2-phenyl-9-quinolyl)selenolate], Zn [2-(C6H5)C9H5NSe]2, have been synthesized. The molecular and crystal structure of the compounds were determined by X-ray structural analysis. The structures of the 2-phenyl-8-quinolylselenol ligand in the molecules of di(2-phenyl-8-quinolyl) diselenide and in the intracomplex compound of zinc are compared. The effect of the phenyl group in position 2 of the quinoline nucleus on the formation of the molecules and their packing in the crystal structure is discussed.

How to Cite
Silina, E.; Belyakov, S.; Ashaks, J.; Tokmakov, A.; Pech, L.; Zaruma, D. Chem. Heterocycl. Compd. 2011, 47(3), 302. [Khim. Geterotsikl. Soedin. 2011, 371.]

For this article in the English edition see DOI 10.1007/s10593-011-0757-5

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Published

2014-12-01

Issue

No. 3 (2011)

Section

Original Papers