DERIVATIVES OF 1,4-DIARYL-5,6,7,8-TETRAHYDRO-2,2a,8a-TRIAZACYCLOPENTA[<i>c,d</i>]AZULENE

Authors

  • А. М. Демченко T. G. Shevchenko Chernigov Pedagogical University

DOI:

https://doi.org/10.1007/300

Keywords:

3-aryl-4, 5-pentamethylene-l, 2, 4-triazoles, α-halogeno ketones, 2a, 8a-triazacyclopenta[c, d]azulene, correlation dependence of proton chemical shifts, cyclization in alkaline media, quaternary phenacylium salts

Abstract

Derivatives of the previously unknown heterocyclic system 2,2a,8a-triazacyclopenta[c,d]azulene were synthesized by condensation of 3-aryl-4,5-pentamethylene-1,2,4-triazoles or 2-(β-aroylhydrazin)-1-aza-Δ-cycloheptene with α-halogeno ketones, followed by cyclization of the intermediate products in alkaline media.

Author: A. M. Demchenko.

English Translation in Chemistry of Heterocyclic Compounds, 2000, 36 (8), pp 985-988

http://link.springer.com/article/10.1007/BF02256986

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Published

2013-02-12

Issue

No. 8 (2000)

Section

Original Papers