3-(NITROMETHYL)-3,4-DIHYDROQUINOXALIN-2(1<i>H</i>)-ONES: SYNTHESIS AND STRUCTURE

Authors

  • Василий В. Пелипко Herzen State Pedagogical University of Russia, 48 Moyka River Embankment, Saint Petersburg 191186
  • Сергей В. Макаренко Herzen State Pedagogical University of Russia, 48 Moyka River Embankment, Saint Petersburg 191186
  • Валентина М. Берестовицкая Herzen State Pedagogical University of Russia, 48 Moyka River Embankment, Saint Petersburg 191186
  • Руслан И. Байчурин Herzen State Pedagogical University of Russia, 48 Moyka River Embankment, Saint Petersburg 191186

DOI:

https://doi.org/10.1007/3285

Keywords:

1, 2-diaminobenzene, ethyl 3-nitroacrylate, 3-(nitromethyl)-3, 4-dihydroquinoxalin-2(1H)-one, quinoxalin-2(1Н)-one, aza-Michael reaction

Abstract

Reactions of ethyl 3-nitroacrylate with о-phenylenediamine and its substituted derivatives were used for the synthesis of 3-(nitromethyl)-3,4-dihydroquinoxalin-2(1H)-ones, followed by structural characterization. These compounds were found to undergo elimination of nitromethane, leading to quinoxalin-2(1H)-ones.

Authors: Vasilii V. Pelipko, Sergey V. Makarenko, Valentina M. Berestovitskaya*, Ruslan I. Baichurin

Author Biographies

Василий В. Пелипко, Herzen State Pedagogical University of Russia, 48 Moyka River Embankment, Saint Petersburg 191186

Василий Васильевич Пелипко

аспирант кафедры органической химии

Сергей В. Макаренко, Herzen State Pedagogical University of Russia, 48 Moyka River Embankment, Saint Petersburg 191186

Сергей Валентинович Макаренко

профессор кафедры органической химии

Валентина М. Берестовицкая, Herzen State Pedagogical University of Russia, 48 Moyka River Embankment, Saint Petersburg 191186

Валентина Михайловна Берестовицкая

заведующая кафедрой органической химии

Руслан И. Байчурин, Herzen State Pedagogical University of Russia, 48 Moyka River Embankment, Saint Petersburg 191186

Руслан Измаилович Байчурин

старший научный сотрудник лаборатории нитросоединений

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Published

2016-08-11

Issue

Vol. 52 No. 8 (2016)

Section

Original Papers