azides, enamines, linear chains of ring systems, 1, 2, 3-triazoles, triazolines
Abstract
The reactions of β-azolyl enamines with azides proceeded under solvent-free conditions in the absence of base at 110°С by one of the possible routes, selectively forming 1,4-disubstituted 1,2,3-triazoles. The proposed reaction mechanism includes cycloaddition of the starting reagents, leading to 1,2,3-triazoline intermediates, followed by elimination of dimethylamine and the formation of aromatic triazole ring.
Author Biography
Татьяна В. Березкина, Ural Federal University named after the first President of Russia B. N. Yeltsin
Ведущий научный сотрудник кафедры технологии органического синтеза
