SYNTHESIS, STRUCTURE, AND ALKYLATION OF N-METHYLMORPHOLINIUM 5-THENOYL- AND 5-BENZOYL-3-CYANO-6-TRIFLUOROMETHYLPYRIDINE-2-THIOLATES
DOI:
https://doi.org/10.1007/490Keywords:
N-methylmorpholine, pyridine, thieno[2, 3-b]pyridine, cyanothioacetamide, ethoxyethylene, alkylationN-methylmorpholine, alkylationAbstract
By reaction of ethoxymethylene derivatives of trifluorothenoyl- and trifluorobenzoylacetone with cyanothioacetamide in the presence of excess N-methylmorpholine, we have obtained the corresponding N-methylmorpholinium 5-acyl-3-cyano-6-trifluoromethylpyridine-2-thiolates and have studied their alkylation.
Authors: Ya. Yu. Yakunin, V. D. Dyachenko, and V. P. Litvinov.
English Translation in Chemistry of Heterocyclic Compounds, 2000, 36 (12), pp 1431-1436