CATALYTIC REACTION OF SUBSTITUTED 1,3-OXATHIOLANES WITH DIAZOCARBONYL COMPOUNDS

Authors

  • Гульнур Н. Сахабутдинова Ufa State Petroleum Technological University, 1 Kosmonavtov St., Ufa 450062, Russia
  • Гульнара З. Раскильдина Ufa State Petroleum Technological University, 1 Kosmonavtov St., Ufa 450062, Russia
  • Ирина П. Байкова Ufa Institute of Chemistry, Ufa Federal Research Center of the Russian Academy of Sciences, 71 Oktyabrya Ave., Ufa 450054, Russia
  • Семен С. Злотский Ufa State Petroleum Technological University, 1 Kosmonavtov St., Ufa 450062, Russia
  • Римма М. Султанова Ufa State Petroleum Technological University, 1 Kosmonavtov St., Ufa 450062, Russia Ufa Institute of Chemistry, Ufa Federal Research Center of the Russian Academy of Sciences, 71 Oktyabrya Ave., Ufa 450054, Russia

DOI:

https://doi.org/10.1007/4999

Keywords:

diazoesters, ylides, 1, 3-oxathiolanes, thietanes, homogeneous catalysis, insertion into the C–S bond, intramolecular rearrangements.

Abstract

The reaction of substituted 1,3-oxathiolanes with diazocarbonyl compounds in the presence of Cu(OTf)2 and Rh2(OAc)4 was studied. The reaction is accompanied by the insertion of an alkoxycarbonylmethylene fragment into the C–S bond of the oxathiolane ring and leads to the formation of heterocyclic and heteroaliphatic products.

Author Biography

Гульнара З. Раскильдина, Ufa State Petroleum Technological University, 1 Kosmonavtov St., Ufa 450062, Russia

Кафедра "Общая, аналитическая и прикладная химия"

Published

2019-12-18

Issue

Section

Original Papers