SONOCHEMICAL SYNTHESIS OF 1',4'-DIALKYL-1',4',5',6'-TETRAHYDROPYRAZINO[2',3':1,9](C60-<i>I</i><sub>h</sub>)[5,6]FULLERENES

Authors

  • Земфира С. Кинзябаева Institute of Petrochemistry and Catalysis, Ufa Federal Research Center of the Russian Academy of Sciences, 141 Oktyabrya St., Ufa 450075, Russia; e-mail: zefa5@rambler.ru

DOI:

https://doi.org/10.1007/6118

Keywords:

fullerene piperazine adducts, secondary acyclic diamines, [4 2] cycloaddition reactions of C60 fullerene, selective sonochemical reactions, ultrasound.

Abstract

For the first time, a selective and efficient method for the synthesis of 1',4'-dialkyl-1',4',5',6'-tetrahydropyrazino[2',3':1,9](С60-Ih)[5,6]-fullerenes (alkyl = methyl, ethyl, isopropyl) was developed based on the reaction of C60 fullerene with N-substituted ethylenediamines in PhMe–DMF medium effected by ultrasound.

 

Author Biography

Земфира С. Кинзябаева, Institute of Petrochemistry and Catalysis, Ufa Federal Research Center of the Russian Academy of Sciences, 141 Oktyabrya St., Ufa 450075, Russia; e-mail: zefa5@rambler.ru

кхн, научный сотрудник лаборатории химии высоких энергии и катализа

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Published

2021-05-27

Issue

Vol. 57 No. 5 (2021)

Section

Short Communications