SYNTHESIS OF CONDENSED 3-CYANOPYRIDIN-2(1<i>H</i>)-ONES BASED ON THE SMILES REARRANGEMENT

Authors

  • Е. Г. Пароникян A. L. Mndzhoyan Institute of Fine Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of the Republic of Armenia
  • А. С. Норавян A. L. Mndzhoyan Institute of Fine Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of the Republic of Armenia
  • Ш. Ш. Дашян A. L. Mndzhoyan Institute of Fine Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of the Republic of Armenia
  • Р. А. Тамазян Molecular Structure Research Center of the Scientific Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of the Republic of Armenia
  • А. Г. Айвазян Molecular Structure Research Center of the Scientific Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of the Republic of Armenia
  • Г. А. Паносян Molecular Structure Research Center of the Scientific Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of the Republic of Armenia

DOI:

https://doi.org/10.1007/651

Keywords:

изохинолин, пирано[3, 4-c]пиридин, пиридин-2(1H)-он, пиридин-2(1H)-тион, перегруппировка Смайлса

Abstract

Condensed 3-cyanopyridin-2(1H)-ones have been synthesized via an intramolecular nucleophilic substitution (Smiles rearrangement). The X-ray structural analysis revealed the existence of intermolecular hydrogen bonding.

Authors: E. G. Paronikyan, A. S. Noravyan, Sh. Sh. Dashyan, R. A. Tamazyan, A. G. Aivazyan, and G. A. Panosyan.

English Translation in Chemistry of Heterocyclic Compounds, 2013, 49 (8), pp 1151-1157

http://link.springer.com/article/10.1007/s10593-013-1357-3

Author Biography

Е. Г. Пароникян, A. L. Mndzhoyan Institute of Fine Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of the Republic of Armenia

ведуший научный сотрудник ИТОХ, д.х.н. проф.

Ervand Garnik Paronikyan

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Published

2013-06-20

Issue

No. 8 (2013)

Section

Original Papers