A NEW METHOD FOR THE SYNTHESIS OF 5-BROMO(ARYL)METHYLENE-SUBSTITUTED HYDANTOINS

Authors

  • Р. Л. Антипин M. V. Lomonosov Moscow State University, Moscow 119992
  • Е. К. Белоглазкина M. V. Lomonosov Moscow State University, Moscow 119992
  • А. Г. Мажуга M. V. Lomonosov Moscow State University, Moscow 119992
  • А. Н. Чернышева M. V. Lomonosov Moscow State University, Moscow 119992
  • Н. В. Зык M. V. Lomonosov Moscow State University, Moscow 119992

DOI:

https://doi.org/10.1007/7207

Keywords:

5-aryl-3, 5-dihydro-4H-2-methylthioimidazol-4-ones, hydantoins, imidazoline-2, 4-diones, bromination, addition-elimination

Abstract

It has been shown that bromination of 5-aryl-5-benzylidene-3,5-dihydro-4H-2-methylthioimidazol-4-one in methylene chloride at room temperature leads to the addition of bromine at the double bond, but the the reaction of 5-aryl-3,5-dihydro-4H-2-methylthio-5-(2-pyridylmethylene)imidazol-4-one gave complex compound of the starting materials. After boiling both of the compounds obtained in ethanol the corresponding 5-[bromo(aryl)methylene]imidazolidine-2,4-diones were obtained.

How to Cite
Antipin, R. L.; Beloglazkina, E. K.; Magouga, A. G.; Chernysheva, A. N.; Zyk, N. V.  Chem. Heterocycl. Compd. 2008, 44, 1135. [Khim. Geterotsikl. Soedin. 2008, 1406.]

For this article in the English edition see DOI 10.1007/s10593-008-0167-5


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Published

2022-11-24

Issue

No. 9 (2008)

Section

Original Papers