SYNTHESIS AND CHARACTERISTICS OF THE MASS SPECTRA OF 2,5-DIMERCAPTO-2,5-DIMETHYLTETRAHYDROTHIOPHENE

Authors

  • Л. Г. Шагун Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Science, Irkutsk 664033
  • Л. В. Клыба Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Science, Irkutsk 664033
  • И. А. Дорофеев Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Science, Irkutsk 664033
  • Е. Р. Жанчипова Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Science, Irkutsk 664033
  • И. А. Михайлова Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Science, Irkutsk 664033
  • М. Г. Воронков Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Science, Irkutsk 664033

DOI:

https://doi.org/10.1007/7672

Keywords:

2, 5-hexanedione, 5, 5-hexanetetrathiol, 5-dimercapto-2, 5-dimethyltetrahydrothiophene, 1-iodopropan-2-one, intramolecular cyclization, mass spectra

Abstract

2,5-Dimercapto-2,5-dimethyltetrahyrothiophene was synthesized by the reaction of 1-iodopropan-2-one with hydrogen sulfide in an ether solution of hydrogen chloride at -70˚C. Its structure was established by mass spectrometry, 1H and 13C NMR spectroscopy.

How to Cite
Shagun, L. G.; Klyba, L. V.; Dorofeev, I. A.; Zhanchipova, E. R.;
Mikhailova, I. A.; Voronkov, M. G.  Chem. Heterocycl. Compd. 2007, 43, 166. [Khim. Geterotsikl. Soedin. 2007, 216.]

For this article in the English edition see DOI 10.1007/s10593-007-0027-8


Downloads

Published

2023-04-03

Issue

No. 2 (2007)

Section

Original Papers