GENERAL ACCESS TO A NOVEL CLASS OF SILYL HETEROCYCLES

Authors

  • A. Degl’Innocenti Department of Organic Chemistry and HBL, University of Florence, 50019 Sesto Fiorentino
  • A. Capperucci Department of Organic Chemistry and HBL, University of Florence, 50019 Sesto Fiorentino
  • I. Malesci Department of Organic Chemistry and HBL, University of Florence, 50019 Sesto Fiorentino
  • M. Acciai Department of Organic Chemistry and HBL, University of Florence, 50019 Sesto Fiorentino
  • G. Castagnoli Department of Organic Chemistry and HBL, University of Florence, 50019 Sesto Fiorentino

DOI:

https://doi.org/10.1007/7730

Keywords:

dithiolanes, organosilanes, oxathiolanes, oxazolidines, silyl heterocycles, thiazolidines

Abstract

2-Trimethylsilyl-substituted five-membered  heterocycles can be accessed through the reaction of bromo(methoxy)methyltrimethylsilane  with 1,2-dithiols, 1,2-mercaptoalcohols, 1,2-mercapto-amines, and 1,2-hydroxyamines, leading  to the formation of several 2-silylated 1,3-dithiolanes, -oxathiolanes, -thiazolidines, and -oxazolidines.

How to Cite
Degl’Innocenti, A.; Capperucci, A.; Malesci, I.; Acciai, M.; Castagnoli, G.  Chem. Heterocycl. Compd. 2006, 42, 1568. [Khim. Geterotsikl. Soedin. 2006, 1838.]

For this article in the English edition see DOI 10.1007/s10593-006-0280-2

Downloads

Published

2023-04-25

Issue

No. 12 (2006)

Section

Original Papers