SYNTHESIS AND PROPERTIES OF AZOLES AND THEIR DERIVATIVES. 57. UNEXPECTED RESULTS OF 3-NITROPROPENE-1 [2+3] CYCLOADDITION TO C,C,N-TRIPHENYLNITRONE

Authors

  • R. Jasiński Institute of Organic Chemistry and Technology Cracow Technical University, 31-155 Kraków
  • M. Kwiatkowska Institute of Organic Chemistry and Technology Cracow Technical University, 31-155 Kraków
  • A. Barański Institute of Organic Chemistry and Technology Cracow Technical University, 31-155 Kraków

DOI:

https://doi.org/10.1007/7784

Keywords:

[2 3] cycloaddition, nitrone, nitropropene, isomerization

Abstract

[2+3] Cycloaddition of 3-nitropropene-1 with C,C,N-triphenylnitrone leads to the mixture of 5-nitromethyl-2,3,3-triphenylisoxazolidine and 5-methyl-4-nitro-2,3,3-triphenylisoxazolidine. The result obtained can be explained assuming that 3-nitropropene-1 isomerizes  to  1-nitro-
propene-1 under reaction conditions.

How to Cite
Jasiński, R.; Kwiatkowska, M.; Barański, A.  Chem. Heterocycl. Compd. 2006, 42, 1334. [Khim. Geterotsikl. Soedin. 2006, 1545.]

For this article in the English edition see DOI 10.1007/s10593-006-0244-6

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Published

2023-05-12

Issue

No. 10 (2006)

Section

Original Papers