SULFENYL HALIDES IN THE SYNTHESIS OF HETEROCYCLES. 3. INTERACTION OF PERFLUORO-1-ETHYL-2-METHYL–1-PROPENYLIMINOCHLOROMETHANESULFENYL CHLORIDE WITH 1-ALLYL-2-METHOXYBENZENE

Authors

  • А. В. Борисов Nizhni Novgorod Technical University, Nizhni Novgorod 603606
  • В. К. Бельский Nizhni Novgorod Technical University, Nizhni Novgorod 603606
  • В. К. Османов Nizhni Novgorod Technical University, Nizhni Novgorod 603606
  • Г. Н. Борисова Nizhni Novgorod Technical University, Nizhni Novgorod 603606
  • Ж. В. Мацулевич Nizhni Novgorod Technical University, Nizhni Novgorod 603606

DOI:

https://doi.org/10.1007/7790

Keywords:

alkenes, sulfenyl chlorides, heterocyclization

Abstract

Reaction of perfluoro-1-ethyl-2-methyl-1-propenyliminochloromethanesulfenyl chloride with 1-allyl-2-methoxybenzene in methylene chloride and  nitromethane gives as the main products  β- and  γ-chloro
sulfides plus derivative of 2,3-dihydrobenzofuran.  The reaction in nitromethane in the presence of lithium perchlorate gave a product of addition of sulfur-containing electrophiles to the double bond – a derivative of 1,3-thiazolidin-2-one – in preference to the cycloaddition product.

How to Cite
Borisov, A. V.; Belsky, V. K.; Osmanov, V. K.; Borisova, G. N.; Matsulevich, Zh. V.  Chem. Heterocycl. Compd. 2006, 42, 1346. [Khim. Geterotsikl. Soedin. 2006, 1558.]

For this article in the English edition see DOI 10.1007/s10593-006-0247-3

 

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Published

2023-05-16

Issue

No. 10 (2006)

Section

Original Papers