REDUCTIVE DEACETYLATION OF 3,3,3-TRIFLUORO-1-(2-THENOYL)ACETONE

Authors

  • Н. В. Руссавская Irkutsk A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk 664033
  • В. А. Грабельных Irkutsk A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk 664033
  • Э. Н. Дерягина Irkutsk A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk 664033
  • Н. А. Корчевин Irkutsk A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk 664033

DOI:

https://doi.org/10.1007/7886

Keywords:

hydrazine, polysulfide anions, 3, 3-trifluoro-1-(2-thenoyl)acetone, deacetylation

Abstract

The reaction of 3,3,3-trifluoro-1-(2-thenoyl)acetone with sulfur–hydrazine hydrate–alkali and hydrazine hydrate–alkali systems is effected by reductive fission of the trifluoroacetyl group and leads  to the formation  of  nitrogen-containing  derivatives  of 2-acetylthiophene. Sodium polysulfide assists the reductive fission of 3,3,3-trifluoro-1-(2-thenoyl)acetone.

How to Cite
Russavskaya, N. V.; Grabel'nyh, V. A.; Deryagina, E. N.; Korchevin, N. A.  Chem. Heterocycl. Compd. 2006, 42, 868. [Khim. Geterotsikl. Soedin. 2006, 1006.]

For this article in the English edition see DOI 10.1007/s10593-006-0171-6


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Published

2023-06-27

Issue

No. 7 (2006)

Section

Original Papers