METAL-COMPLEX CATALYSIS DURING THE REDUCTION OF FUNCTIONAL GROUPS BY SODIUM BOROHYDRIDE IN THE SYNTHESIS OF PYRROLIDINE DERIVATIVES

Authors

  • А. О. Мартиросян A. L. Mndzhoyan Institute of Fine Organic Chemistry, National Academy of Sciences of the Republic of Armenia, Erevan
  • В. Е. Оганесян A. L. Mndzhoyan Institute of Fine Organic Chemistry, National Academy of Sciences of the Republic of Armenia, Erevan
  • С. П. Гаспарян A. L. Mndzhoyan Institute of Fine Organic Chemistry, National Academy of Sciences of the Republic of Armenia, Erevan
  • С. С. Мамян Center of Research on the Structure of Molecules, National Academy of Sciences of the Republic of Armenia, Erevan
  • Р. К. Казарян M. Heratsi Erevan Medical University, Erevan
  • В. Н. Мадакян M. Heratsi Erevan Medical University, Erevan

DOI:

https://doi.org/10.1007/8054

Keywords:

sodium borohydride, copper and cobalt complexes, metal-complex catalysis, pyrrolidines, porphyrins, reduction

Abstract

A selective method was developed for the reduction of functional groups with sodium borohydride using complexes of CoCl2 and CuCl2 with triethylbenzylammonium chloride and cobalt and copper meso-tetra[4-(2-hydroxyethyl)pyridyl]porphyrinates as catalysts.

How to Cite
Martirosyan, A. O.; Hovhanesyan, V. E.; Gasparyan, S. P.; Mamayan, S. S.; Ghazaryan, R. K.; Madakyan, V. N.  Chem. Heterocycl. Compd. 2006, 42, 180. [Khim. Geterotsikl. Soedin. 2006, 205.]

For this article in the English edition, see DOI 10.1007/s10593-006-0068-4

 

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Published

2023-09-15

Issue

No. 2 (2006)

Section

Original Papers