REACTIONS OF 3-NITRO-1,2,4-TRIAZOLE DERIVATIVES WITH ALKYLATING AGENTS. 2. ALKYLATION OF A NEUTRAL HETEROCYCLE BY DIMETHYL SULFATE

Authors

  • Г. Т. Суханов Institute of Problems of Chemical Energetic Technologies, Siberian Branch of the Russian Academy of Sciences, 659322 Biisk
  • Г. В. Сакович Institute of Problems of Chemical Energetic Technologies, Siberian Branch of the Russian Academy of Sciences, 659322 Biisk
  • А. Г. Суханова Federal Research and Production Center "Altai", 659322 Biisk
  • А. Ю. Лукин Federal Research and Production Center "Altai", 659322 Biisk

DOI:

https://doi.org/10.1007/8213

Keywords:

N-alkyl-3-nitro-1, 2, 4-triazole, N, N-dimethyl-1, 4-triazol-5-one, alkylation, regioselectivity

Abstract

The reaction of 3-nitro-1,2,4-triazole and 5-methyl-3-nitro-1,2,4-triazole with dimethyl sulfate leads to mixtures of N-mono- and N,N-dimethylnitrotriazolium compounds and products of the subsequent conversion of the latter, namely, N,N-dimethyl-1,2,4-triazol-5-ones.

How to Cite
Sukhanov, G. T.; Sakovich, G. V.; Sukhanova, A. G.; Lukin, A. Yu.  Chem. Heterocycl. Compd. 2005, 41, 994. [Khim. Geterotsikl. Soedin. 2005, 1168.]

For this article in the English edition, see DOI 10.1007/s10593-005-0266-5


Downloads

Published

2023-10-27

Issue

No. 8 (2005)

Section

Original Papers