REACTION OF 10-METHYL(PHENYL)-5,10-DIHYDROPHENARSAZINE 10-OXIDES WITH HYDRIODIC ACID

Authors

  • V. I. Gavrilov Kazan State Technical University, Kazan 420015
  • A. A. Karavanov Kazan State Technical University, Kazan 420015
  • R. R. Musin Kazan State Technical University, Kazan 420015
  • F. R. Garieva Kazan State Technical University, Kazan 420015
  • R. Z. Musin A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center, Russian Academy of Sciences, Kazan 420088

Keywords:

hydriodic acid, 10-methyl-5,10-dihydrophenarsazine 10-oxide, 10-phenyl-5,10-dihydrophenarsazine 10-oxide, mass spectra

Abstract

We have studied the reaction of 10-methyl(phenyl)-5,10-dihydrophenarsazine 10-oxides with hydriodic acid and we have established the structure of the products by high-resolution mass spectrometry. We have shown that when the methyl group is replaced by a phenyl group in 5,10-dihydrophenarsazine 10-oxides, cleavage of the endocyclic arsenic–carbon bonds occurs.

How to Cite
Gavrilov, V. I.; Karavanov, A. A.; Musin, R. R.; Garieva, F. R.; Musin, R. Z. Chem. Heterocycl. Compd. 2004, 40, 1212. [Khim. Geterotsikl. Soedin. 2004, 1396.]

For this article in the English edition, see DOI https://doi.org/10.1023/B:COHC.0000048297.35826.d3

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Published

2004-09-25

Issue

No. 9 (2004)

Section

Original Papers