N-AMINO DERIVATIVES OF CONDENSED IMIDAZOLE SYSTEMS
Keywords:
N-aminoazoles, O-picrylhydroxylamine, conformations of the N-amino group, X-ray structural analysis, electrophilic aminationAbstract
The previously unknown 1-amino- and 3-aminonaphtho[1,2-d]imidazoles, 1-aminonaphtho[2,3-d]-imidazole, 1-aminophenanthro[9,10-d]imidazole and the N-amino-N'-methylimidazolium picrates corresponding to them have been obtained by direct amination of a series of condensed imidazoles with O-picrylhydroxylamine. An X-ray structural investigation of 1-amino- 3-methylnaphtho[1,2-d]-imidazolium picrate showed that, in difference to 1-aminobenzimidazolium salts, a conformation exists in it in which the hydrogen atoms of the N–NH2 group are directed to the side of the meso carbon atom.
How to Cite
Koroleva, M. G.; Dyablo, O. V.; Pozharskii, A. F.; Starikova, Z. A. Chem. Heterocycl. Compd. 2003, 39, 1161. [Khim. Geterotsikl. Soedin. 2003, 1324.]
For this article in the English edition, see DOI 10.1023/B:COHC.0000008260.31382.77
