REACTIONS OF γ-SULTINES WITH ELECTROPHILIC REAGENTS. 3. CHLORINATION OF 3,5-DIARYL-1,2-OXATHIOLANE 2-OXIDES

Authors

  • Е. В. Григорьев M. V. Lomonosov Moscow State University, 119234 Moscow
  • Л. Г. Сагинова M. V. Lomonosov Moscow State University, 119234 Moscow
  • И. Ю. Клейменова M. V. Lomonosov Moscow State University, 119234 Moscow

Keywords:

1,3-diaryl-1,3-dichloropropanes, diastereomers, 3-chloro-1,3-diphenylpropanesulfonyl chloride, 1,2-oxathiolane 2-oxides (γ-sultines), diastereoselectivity, chlorination

Abstract

The influence of the nature of the aryl substituents and the reaction conditions for the chlorination of 3,5-diphenyl-1,2-oxathiolane 2-oxide and 3,5-bis(4-methoxyphenyl)-1,2-oxathiolane 2-oxide have been studied. Possible mechanisms for the chlorination of γ-sultines are discussed.

How to Cite
Grigoryev, E. V.; Saginova, L. G.; Kleymenova, I. Yu. Chem. Heterocycl. Compd. 2003, 39, 911. [Khim. Geterotsikl. Soedin. 2003, 1053.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1026150522201

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Published

2003-07-25

Issue

No. 7 (2003)

Section

Original Papers