NUCLEOPHILIC SUBSTITUTION REACTIONS OF 2,4,6-TRIS(TRINITROMETHYL)-1,3,5-TRIAZINE. 3. REACTION OF 2,4,6-TRIS(TRINITROMETHYL)-1,3,5-TRIAZINE WITH AZIDES AND HYDRAZINE

Authors

  • А. В. Шастин Institute of the Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka 142432, Moscow region
  • Т. И. Годовикова N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 119991
  • Б. Л. Корсунский N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 119991

Keywords:

sodium azide, hydrazine, trimethylsilyl azide, 2,4,6-tris(trinitromethyl)-1,3,5-triazine, nucleophilic substitution

Abstract

As a result of nucleophilic substitution of the trinitromethyl groups in 2,4,6-tris(trinitromethyl)-1,3,5-triazine, the corresponding monoazido and diazido derivatives have been synthesized. The reaction of the starting triazine with hydrazine acetate in the presence of trifluoroacetic acid leads to 1-acetyl-2,2-bis[4,6-bis(trinitromethyl)-1,3,5-triazin-2-yl]hydrazine.

How to Cite
Shastin, A. V.; Godovikova,T. I.; Korsunskii, B. L. Chem. Heterocycl. Compd. 2003, 39, 354. [Khim. Geterotsikl. Soedin. 2003, 400.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1023970928207

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Published

2003-03-25

Issue

No. 3 (2003)

Section

Original Papers