INVESTIGATION OF THE REACTION OF 3,5-DIAMIDINO-4-NITROPYRAZOLE WITH AMINES

Authors

  • B. А. Макаров NIOPIK State Scientific Center of the Russian Federation, Moscow 103787
  • O. Б. Рябова NIOPIK State Scientific Center of the Russian Federation, Moscow 103787
  • Л. M. Алексеева NIOPIK State Scientific Center of the Russian Federation, Moscow 103787
  • B. B. Чернышев Moscow M. V. Lomonosov State University, Moscow 119899
  • B. Г. Граник NIOPIK State Scientific Center of the Russian Federation, Moscow 103787

Keywords:

DMF acetal, 4-nitropyrazole, formamidine, X-ray crystallographic analysis

Abstract

The interaction of 3,5-bis(N,N-dimethylaminomethylene)amino-1-methyl-4-nitropyrazole with amines proceeds regioselectively with the formation of 3-amino-5-(N,N-dimethylaminomethylene)amino-1-methyl-4-nitropyrazole. Amines are converted in this way into N,N-dimethylformamidine derivatives. The structures of the compounds obtained were proved by 1H and 13C NMR spectroscopy and by X-ray crystallographic analysis.

How to Cite
Makarov, V. A.; Ryabova, O. B.; Alekseeva, L. M.; Chernyshev, V. V.; Granik, V. G. Chem. Heterocycl. Compd. 2002, 38, 947. [Khim. Geterotsikl. Soedin. 2002, 1087.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1020921530209

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Published

2002-08-25

Issue

No. 8 (2002)

Section

Original Papers