SYNTHESIS AND CRYSTAL STRUCTURE OF 2,3-BIS(DINITROFLUOROMETHYL)-1,4-DIOXANE

Authors

  • Б. С. Федоров Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka; State Scientific-Research Institute Kristall, Dzerzhinsk
  • Н. И. Головина Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka; State Scientific-Research Institute Kristall, Dzerzhinsk
  • С. П. Смирнов Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka; State Scientific-Research Institute Kristall, Dzerzhinsk
  • И. Ш. Абдрахманов Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka; State Scientific-Research Institute Kristall, Dzerzhinsk
  • А. И. Фиркин Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka; State Scientific-Research Institute Kristall, Dzerzhinsk
  • Л. О. Атовмян Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka. State Scientific-Research Institute Kristall, Dzerzhinsk

Keywords:

ammonium fluoroxysulfate, 2,3-bis(dinitrofluoromethyl)-1,4-dioxane, X-ray diffraction analysis, fluorination

Abstract

For the first time the dinitromethyl group was modified to dinitrofluoromethyl group in the series of aliphatic polynitro compounds in the case of the reaction of 1,1,4,4-tetranitro-2,3-butanediol diacetate with ammonium fluoroxysulfate in the presence of sodium bicarbonate and ethylene glycol. Previously unknown 2,3-bis(dinitrofluoromethyl)-1,4-dioxane was synthesized. Its structure was determined by X-ray diffraction analysis.

How to Cite
Fedorov, B. S.; Golovina, N. I.; Smirnov, S. P.; Abdrakhmanov, I. Sh.; Firkin, A. I.; Atovmyan, L. O. Chem. Heterocycl. Compd. 2002, 38, 385. [Khim. Geterotsikl. Soedin. 2002, 450.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1016014802080

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Published

2002-04-25

Issue

No. 4 (2002)

Section

Original Papers