<i>sym</i>-TRIAZINE DERIVATIVES. 2. SYNTHESIS, PROPERTIES, AND STRUCTURE OF 2-OXO-1,2-DIHYDRO-<i>sym</i>-TRIAZINES

Authors

  • С. Н. Михайличенко Kuban State Agricultural University, Krasnodar 350044
  • А. А. Чеснюк Kuban State Agricultural University, Krasnodar 350044
  • B. E. Заводник L. Ya. Karpov Physico-Chemical Science Research Institute, Moscow 103064
  • С. И. Фирганг N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 117913
  • Л. Д. Конюшкин N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 117913
  • B. Н. Заплишный Kuban State Agricultural University, Krasnodar 350044

Keywords:

2-oxo-1,2-dihydro-sym-triazines, alkylation, X-ray analysis

Abstract

Previously unreported 2-oxo-1,2-dihydro-sym-triazines have been prepared and their alkylation reactions have been studied. It was found that, independently of the structure and nature of the substituent in positions 4 and 6 of the triazine ring or the structure of the alkyl halide used, the reaction occurs regioselectively at the oxygen atom. The stereostructure of the 2-oxo-1,2-dihydro-sym-triazines was investigated by X-ray analysis and it was shown that they exist as dimers in the crystalline state.

How to Cite
Mikhailichenko, S. N.; Chesniyuk, A. A.; Zavodnik, V. E.; Firgand, S. I.; Konyushkin, L. D.; Zaplishny, V. N. Chem. Heterocycl. Compd. 2002, 38, 292. [Khim. Geterotsikl. Soedin. 2002, 326.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1015631203046

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Published

2002-03-25

Issue

No. 3 (2002)

Section

Original Papers