SYNTHESIS AND PROPERTIES OF 2-(DIORGANYLPHOSPHORYLHYDROXYMETHYL)-1-ORGANYLIMIDAZOLES

Authors

  • Н. К. Гусарова A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664033
  • С. Н. Арбузова A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664033
  • А. М. Реуцкая A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664033
  • Н. И. Иванова A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664033
  • Л. В. Байкалова A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664033
  • Л. М. Синеговская A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664033
  • Н. Н. Чипанина A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664033
  • А. В. Афонин A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664033
  • И. А. Зырянова A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664033

Keywords:

diorganylphosphine oxides, 2-(diorganylphosphorylhydroxymethyl)-1-organylimidazoles, 1-organyl-2-formylbenzimidazoles, 1-organyl-2-formylimidazoles, camphorsulfonic acid, phosphorylation, sulfonates, complexes

Abstract

1-Organyl-2-formylimidazoles and -benzimidazoles react with diorganylphosphine oxides under mild conditions (room temperature, dioxane, 1 h) to give in practically quantitative yields 2-(diorganylphosphorylhydroxymethyl)-1-organylimidazoles – highly reactive synthons and polydentate ligands for the design of metal complex catalysts.

How to Cite
Gusarova, N. K.; Arbuzova, S. N.; Reutskaya, A. M.; Ivanova, N. I.; Baikalova, L. V.; Sinegovskaya, L. M.; Chipanina, N. N.; Afonin, A. V.; Zyryanova, I. A. Chem. Heterocycl. Compd. 2002, 38, 65. [Khim. Geterotsikl. Soedin. 2002, 71.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1014855309771

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Published

2002-01-25

Issue

No. 1 (2002)

Section

Original Papers