HOMOLYTIC ADDITION REACTION OF VINYLSULFONYLFLUOROBENZENE

Authors

  • С. В. Амосова A. E. Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664033
  • Г. М. Гаврилова A. E. Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664033
  • В. И. Гостевская A. E. Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664033
  • А. В. Афонин A. E. Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664033
  • И. А. Ушаков Irkutsk State Technical University, Irkutsk 664074
  • С. Ю. Кузнецова Irkutsk State Technical University, Irkutsk 664074
  • В. К. Воронов Irkutsk State Technical University, Irkutsk 664074

Keywords:

vinylsulfonylfluorobenzene, tetrahydrofuran, homolytic addition, radical initiation

Abstract

The reaction of 3,6-bis(vinylsulfonyl)-1,2,4,5-tetrafluorobenzene with a large excess of tetrahydrofuran at 50-55°C gives the homolytic addition product 3,6-bis[2-(2-tetrahydrofuryl)ethylsulfonyl]-1,2,4,5-tetrafluorobenzene. The reaction is effected by peroxides radical process initiators obtained by the autooxidation of tetrahydrofuran.

How to Cite
Amosova, S. V.; Gavrilova, G. M.; Gostevskaya, V. I.; Afonin, A. V.; Ushakov, I. A.; Kuznetsova, S. Yu.; Voronov, V. K. Chem. Heterocycl. Compd. 2002, 38, 35. [Khim. Geterotsikl. Soedin. 2002, 40.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1014895023883

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Published

2002-01-25

Issue

No. 1 (2002)

Section

Original Papers