TRIMETHYLENE-BRIDGED TETRAORGANODISTANNOXANES {[Me<sub>3</sub>SiCH<sub>2</sub>(RCOO)Sn(CH<sub>2</sub>)<sub>3</sub>Sn(OOCR)CH<sub>2</sub>SiMe<sub>3</sub>]O}<sub>n</sub> (R = Ph, 2,4-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>): CONTROL OF STRUCTURE BY VARIATION OF R

Authors

  • B. Costisella Lehrstuhl fur Anorganische Chemie II der Universitat Dortmund, D-44221 Dormund
  • D. Dakternieks Centre for Chiral and Molecular Technologies, Deakin University, Geelong, Victoria 3217
  • K. Jurkschat Lehrstuhl fur Anorganische Chemie II der Universitat Dortmund, D-44221 Dormund
  • M. Mehring Lehrstuhl fur Anorganische Chemie II der Universitat Dortmund, D-44221 Dormund
  • I. Paulus Lehrstuhl fur Anorganische Chemie II der Universitat Dortmund, D-44221 Dormund
  • M. Schürmann Lehrstuhl fur Anorganische Chemie II der Universitat Dortmund, D-44221 Dormund

Keywords:

distannoxanes, X-ray structure

Abstract

The synthesis of the trimethylene-bridged, carboxylate-substituted tetraorga-nodistannoxanes {[Me3SiCH2(RCOO)Sn(CH2)3Sn(OOCR)CH2SiMe3]O}n (1, R = Ph; 2, R = 2,4-Me2C6H3) is reported. Depending on the structure of R, in the solid state these compounds are either dimers (1, n = 2, cis-isomer) with a ladder-type structure or tetramers (2, n = 4) with a double ladder-type structure.

How to Cite
Costisella, B.; Dakternieks, D.; Jurkschat, K.; Mehring, M.; Paulus, I.; Schürmann, M. Chem. Heterocycl. Compd. 2001, 37, 1405. [Khim. Geterotsikl. Soedin. 2001, 1535.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1017907419300

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Published

2001-11-25

Issue

No. 11 (2001)

Section

Original Papers