REACTION OF SUBSTITUTED 1,3,2-DIOXABOROLANES WITH ACETONITRILE

Authors

  • В. В. Кузнецов A. V. Bogatsky Physical Chemistry Institute, National Academy of Sciences of Ukraine, Odessa 270080
  • Ю. Э. Брусиловский A. V. Bogatsky Physical Chemistry Institute, National Academy of Sciences of Ukraine, Odessa 270080
  • А. В. Мазепа A. V. Bogatsky Physical Chemistry Institute, National Academy of Sciences of Ukraine, Odessa 270080

Keywords:

2-alkyl-1,3,2-dioxaboranes, 2-alkoxy-1,3,2-dioxyborolanes

Abstract

Reaction of 2-alkyl- and 2-alkoxy-4,4,5,5-tetramethyl- and 4,5-diphenyl-1,3,2-dioxaborolanes with acetonitrile leads to the corresponding 2-oxazolines. Their yield is determined by the nature of the substituent on the boron atom in the molecule of the starting cyclic boric ester. The results obtained are consistent with calculated values of the relative stability for the intermediate ions (AM1).

How to Cite
Kuznetsov, V. V.; Brusilovskii, Yu. E.; Mazepa, A. V. Chem. Heterocycl. Compd. 2001, 37, 920. [Khim. Geterotsikl. Soedin. 2001, 998.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1012424229830

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Published

2001-07-25

Issue

No. 7 (2001)

Section

Original Papers