SYNTHESIS AND PROPERTIES OF AMMONIUM 5-BENZOYL-4-(2-CHLOROPHENYL)-3-CYANO-6-HYDROXY-6-PHENYL-1,4,5,6-TETRAHYDROPYRIDINE-2-THIOLATES

Authors

  • С. Г. Кривоколыско Taras Shevchenko Lugansk State Pedagogical University, Lugansk 348011
  • B. Д. Дяченко Taras Shevchenko Lugansk State Pedagogical University, Lugansk 348011
  • А. И. Чернега Institute of Organic Chemistry, Ukraine National Academy of Sciences, Kiev 253660
  • B. П. Литвинов N. D. Zelinsky Institute of Organic Chemistry, Russain Academy of Sciences, Moscow 117913

Keywords:

substituted 1,4,5,6-tetrahydropyridine-2-thiolates, ring opening under the effect of aminating agents

Abstract

The reaction of 2-chlorobenzaldehyde with cyanothioacetamide and dibenzoylmethane in the presence of piperidine or N-methylmorpholine gave the corresponding 5-benzoyl-4-(2-chlorophenyl)-3-cyano-6-hydroxy-6-phenyl-1,4,5,6-tetrahydropyridine-2-thiolates, used in the synthesis of 1-alkylthio-4-benzoyl-1-benzoylamino-3-(2-chlorophenyl)-2-cyanobut-1-enes.

How to Cite
Krivokolysko, S. G.; Dyachenko, V. D.; Chernega, A. N.; Litvinov, V. P. Chem. Heterocycl. Compd. 2001, 37, 727. [Khim. Geterotsikl. Soedin. 2001, 790.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1011969413764

Published

2001-06-25

Issue

Section

Original Papers