NOVEL STEREOSELECTIVE SYNTHESIS AND MOLECULAR AND CRYSTALLINE STRUCTURE OF 3-ALLYL-4-(4-BROMOPHENYL)-3-CYANO-6-OXOPIPERIDINE-2-THIONE

Authors

  • С. Г. Кривоколыско Taras Shevchenko State Pedagogical University, Lugansk 348011
  • В. Д. Дяченко Taras Shevchenko State Pedagogical University, Lugansk 348011
  • В. Н. Нестеров A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 117813
  • В. П. Литвинов N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 117913

Keywords:

3-allyl-4-(4-bromophenyl)-3-cyano-6-oxopiperidine-2-thione, X-ray structural investigation

Abstract

The stereoselective synthesis of 3-allyl-4-(4-bromophenyl)- 3-cyano-6-oxopiperidine-2-thione has been carried out by refluxing N-methylmorpholinium 5-[1-(4-bromophenyl)-2-cyano-2-thiocarbamoylethyl]-2,2-dimethyl-1,3-dioxa-6-oxo-4-cyclohexen-4-olate with allyl bromide in ethanol. The structure of the product was confirmed by X-ray investigation.

How to Cite
Krivokolysko, S. G.; Dyachenko, V. D.; Nesterov, V. N.; Litvinov, V. P. Chem. Heterocycl. Compd. 2001, 37, 315. [Khim. Geterotsikl. Soedin. 2001, 344.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1017555032309

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Published

2001-03-25

Issue

No. 3 (2001)

Section

Original Papers