SYNTHESIS OF SUBSTITUTED 6-(1<i>Н</i>-1,2,3-TRIAZOL-1-YL)-4,7-DIHYDRO-1,3,5-DIOXAZEPINES
DOI:
https://doi.org/10.1007/1855Keywords:
5-nitro-1, 3-dioxanes, geminal nitro azides, 1, 2, 3-triazoles, 3, 5-dioxazepines, triethyl phosphite, oxydative azidation, 3-dipolar cycloaddition, deoxygenationAbstract
A convenient method of synthesis of 6-(1Н-1,2,3-triazol-1-yl)-4,7-dihydro-1,3,5‑dioxazepines has been developed that involves deoxygenation reaction of 1-(5-nitro-1,3‑dioxan-5-yl)-1Н-1,2,3-triazoles using triethyl phosphite.
How to Cite
Rudakov, G. F.; Dubovis, M. V.; Kulagin, A. S.; Tsar'kova, K. V.; Goloveshkin, A. S.; Zhilin, V. F. Chem. Heterocycl. Compd. 2015, 50, 1634. [Khim. Geterotsikl. Soedin. 2015, 1777.]
For this article in the English edition see DOI 10.1007/s10593-014-1633-x