SYNTHESIS OF SUBSTITUTED 6-(1<i>Н</i>-1,2,3-TRIAZOL-1-YL)-4,7-DIHYDRO-1,3,5-DIOXAZEPINES

Authors

  • Г. Ф. Рудаков Mendeleev University of Chemical Technology of Russia, 9 Miusskaya square, Moscow 125047, Russian Federation
  • М. В. Дубовис Mendeleev University of Chemical Technology of Russia, 9 Miusskaya square, Moscow 125047, Russian Federation
  • А. С. Кулагин Mendeleev University of Chemical Technology of Russia, 9 Miusskaya square, Moscow 125047, Russian Federation
  • К. В. Царькова Mendeleev University of Chemical Technology of Russia, 9 Miusskaya square, Moscow 125047, Russian Federation
  • А. С. Головешкин Mendeleev University of Chemical Technology of Russia, 9 Miusskaya square, Moscow 125047, Russian Federation
  • В. Ф. Жилин Mendeleev University of Chemical Technology of Russia, 9 Miusskaya square, Moscow 125047, Russian Federation

DOI:

https://doi.org/10.1007/1855

Keywords:

5-nitro-1, 3-dioxanes, geminal nitro azides, 1, 2, 3-triazoles, 3, 5-dioxazepines, triethyl phosphite, oxydative azidation, 3-dipolar cycloaddition, deoxygenation

Abstract

A convenient method of synthesis of 6-(1Н-1,2,3-triazol-1-yl)-4,7-dihydro-1,3,5‑dioxazepines has been developed that involves deoxygenation reaction of 1-(5-nitro-1,3‑dioxan-5-yl)-1Н-1,2,3-triazoles using triethyl phosphite.

How to Cite
Rudakov, G. F.; Dubovis, M. V.; Kulagin, A. S.; Tsar'kova, K. V.; Goloveshkin, A. S.; Zhilin, V. F. Chem. Heterocycl. Compd. 2015, 50, 1634. [Khim. Geterotsikl. Soedin. 2015, 1777.]

For this article in the English edition see DOI 10.1007/s10593-014-1633-x

Author Biographies

Г. Ф. Рудаков, Mendeleev University of Chemical Technology of Russia, 9 Miusskaya square, Moscow 125047, Russian Federation

Геннадий Федорович Рудаков

старший преподаватель кафеды "Химии и технологии органических соединений азота"

М. В. Дубовис, Mendeleev University of Chemical Technology of Russia, 9 Miusskaya square, Moscow 125047, Russian Federation

Михаил Вадимович Дубовис

А. С. Кулагин, Mendeleev University of Chemical Technology of Russia, 9 Miusskaya square, Moscow 125047, Russian Federation

Александр Сергеевич Кулагин

К. В. Царькова, Mendeleev University of Chemical Technology of Russia, 9 Miusskaya square, Moscow 125047, Russian Federation

Ксения Валерьевна Царькова

А. С. Головешкин, Mendeleev University of Chemical Technology of Russia, 9 Miusskaya square, Moscow 125047, Russian Federation

Александр Сергеевич Головешкин

В. Ф. Жилин, Mendeleev University of Chemical Technology of Russia, 9 Miusskaya square, Moscow 125047, Russian Federation

Виктор Федорович Жилин

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Published

2014-11-21

Issue

No. 11 (2014)

Section

Original Papers