REACTIONS OF (<i>S</i>)-(4-NITROPHENYL)[(4<i>S</i>)-2-OXO-1,3-OXAZOLIDIN-4-YL]METHYL METHANESULFONATE WITH ALKALI METAL HALIDES AND LITHIUM HYDROXIDE. SYNTHESIS OF [(2<i>R</i>,3<i>R</i>)-3-(4-NITROPHENYL)AZIRIDIN-2-YL]METHANOL

Authors

  • М. Мадесклер University of Auvergne
  • П. Кудер University of Auvergne
  • Ф. Леаль University of Auvergne
  • С. Таррит University of Auvergne
  • Ю. В. Зайцева Samara State University
  • В. П. Зайцев Samara State University

DOI:

https://doi.org/10.1007/245

Keywords:

aziridine, oxazolidin-2-one, recyclization

Abstract

The formation [(2R,3R)-3-(4-nitrophenyl)aziridin-2-yl]methanol and 2-oxazolidine ring opening occurrred in the reaction of (S)-(4-nitrophenyl)[(4S)-2-oxo-1,3-oxazolidin-4-yl]methyl methanesulfonate with lithium hydroxide in aqueous dioxane or under phase transfer catalysis conditions.

Authors: M. Madesclaire, P. Coudert, F. Leal, S. Tarrit, Yu. V. Zaitseva, and V. P. Zaitsev.

English Translation in Chemistry of Heterocyclic Compounds, 2013, 49 (8), pp 1103-1107

http://link.springer.com/article/10.1007/s10593-013-1350-x

Author Biographies

М. Мадесклер, University of Auvergne

Мишель Мадесклер

П. Кудер, University of Auvergne

Паскаль Кудер

Ф. Леаль, University of Auvergne

Фернанд Леаль

С. Таррит, University of Auvergne

Себастьян Таррит

Ю. В. Зайцева, Samara State University

Юлия Валерьевна Зайцева

В. П. Зайцев, Samara State University

Валерий Петрович Зайцев

Published

2013-08-14

Issue

Section

Original Papers