HYDROSILYLATION OF ALLYL ESTERS OF MONOSACCHARIDES

Authors

  • Н. Н. Сидамонидзе Iv. Javakhishvili Tbilisi State University, Tbilisi 0128
  • Л. К. Джаниашвили Iv. Javakhishvili Tbilisi State University, Tbilisi 0128
  • Р. О. Вардиашвили Iv. Javakhishvili Tbilisi State University, Tbilisi 0128
  • М. О. Исакадзе Iv. Javakhishvili Tbilisi State University, Tbilisi 0128

DOI:

https://doi.org/10.1007/8120

Keywords:

hydrosilylation, monosaccharides, allyl esters, cyclodisilazanes, deacetylation

Abstract

By hydrosilylation of 1-O-allyl-2,3,4,6-tetra-O-acetyl-β-D-glucopyranose and 1-O-allyl-2,3,4,6-tetra-O-acetyl-β-D-galactopyranose with 1,3-bis(dimethylsilyl)-2,2,4,4-tetramethylcyclodisilazane in the presence of the catalyst  Co2(CO)8, we have obtained 1,3-di[3-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)propyldimethylsilyl]-2,2,4,4-tetramethylcyclodisilazane and  1,3-di[3-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyloxy)propyldimethylsilyl]-2,2,4,4-tetramethylcyclodisilazane. By deacetylation, we obtained 1,3-di[3-(β-D-glucopyranosyloxy)propyldimethylsilyl]-2,2,4,4-tetramethyl-cyclodisilazane.

How to Cite
Sidamonidze, N. N.; Janiashvili, L. K.; Vardiashvili, R. O.; Isakadze, M. O.  Chem. Heterocycl. Compd. 2005, 41, 1534. [Khim. Geterotsikl. Soedin. 2005, 1859.]

For this article in the English edition, see DOI 10.1007/s10593-006-0033-2


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Published

2023-10-13

Issue

No. 12 (2005)

Section

Original Papers