TRISUBSTITUTED 1,3,5-TRIAZINES. 6. SYNTHESIS OF 2,4,6-TRIS(ACETONYL)-1,3,5-TRIAZINE

Authors

  • А. В. Шастин Institute of the Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka 142432, Moscow region
  • Т. И. Годовикова N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 119991
  • Б. Л. Корсунский N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 119991

Keywords:

2,4,6-tris(acetonyl)-1,3,5-triazine, 2,4,6-tris(tert-butoxycarbonylmethyl)-1,3,5-triazine, tert-butoxycarbonyl group, acylation

Abstract

Acylation of 2,4,6-tris(tert-butoxycarbonylmethyl)-1,3,5-triazine with acetic anhydride in the presence of lithium hydride with subsequent removal of the tert-butoxycarbonyl groups with trifluoroacetic acid leads to 2,4,6-tris(acetonyl)-1,3,5-triazine, the cyclic analog of α-cyanoacetone. The special spectral features of this compound compared with triazines obtained previously are discussed.

How to Cite
KShastin, A. V.; Godovikova, T. I.; Korsunskii, B. L. Chem. Heterocycl. Compd. 2003, 39, 1037. [Khim. Geterotsikl. Soedin. 2003, 1190.]

For this article in the English edition, see DOI 10.1023/B:COHC.0000003521.99022.fb

Downloads

Published

2003-08-25

Issue

No. 8 (2003)

Section

Original Papers