SYNTHESIS, STRUCTURE, AND ALKYLATION OF N-METHYLMORPHOLINIUM 5-[2-CYANOETHYL-1-(4-HYDROXY-3-METHOXYPHENYL)-2-THIOCARBAMOYL]-2,2-DIMETHYL-6-OXO-1,3-DIOXA-4-CYCLOHEXEN-4-OLATE

Authors

  • C. Г. Кривоколыско Eastern Ukraine State University, Lugansk 91034
  • А. Н. Чернега Institute of Organic Chemistry, Ukraine National Academy of Sciences, Kiev, 02094
  • В. П. Литвинов N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 117913

Keywords:

4-hydroxy-3-methoxybenzaldehyde, Meldrum's acid, tetrahydropyridines, cyanothioacetamide, cyclohexan-4-olate, X-ray crystallographic analysis

Abstract

N-Methylmorpholinium 5-[2-cyanoethyl-1-(4-hydroxy-3-methoxyphenyl)-2-thiocarbamoyl]-2,2-dimethyl-6-oxo-1,3-dioxa-4-cyclohexen-4-olate was obtained from the reaction of 4-hydroxy-3-methoxybenzaldehyde with cyanothioacetamide and Meldrum's acid in the presence of N-methylmorpholine. The molecular and crystal structure of the title compound have been established and its alkylation has been studied.

How to Cite
Krivokolysko, S. G.; Chernega, A. N.; Litvinov, V. P. Chem. Heterocycl. Compd. 2002, 38, 1269. [Khim. Geterotsikl. Soedin. 2002, 1438.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1021745916815

Downloads

Published

2002-10-25

Issue

No. 10 (2002)

Section

Original Papers