Synthesis and properties of azoles and their derivatives. 36. Kinetics of the [2+3]-cycloaddition of 1-decene to di- and triphenyl nitrones

Authors

  • А. Бараньски Institute Chemii i Technologii Organiczney, Politechnika Krakowska im. Tadeusza Kosciuszki, 35–155 Krakow
  • B. Таборски Institute Chemii i Technologii Organiczney, Politechnika Krakowska im. Tadeusza Kosciuszki, 35–155 Krakow
  • А. Бодура Institute Chemii i Technologii Organiczney, Politechnika Krakowska im. Tadeusza Kosciuszki, 35–155 Krakow

Abstract

The kinetics of the [2+3]-cycloaddition of 1-decene to C,C,N-triphenyl and Z-C,C-diphenyl nitrones were studied by liquid chromatography. The kinetic and thermodynamic parameters of the reaction were determined. By coomparative analysis of the experimental results it was shown that the steric effects have a significant effect on the dipolarophilic activity of the nitrones in the reaction with 1-decene.

How to Cite
Baranski, A.; Taborski, W.; Bodura, A. B. Chem. Heterocycl. Compd. 1998, 34, 344. [Khim. Geterotsikl. Soedin. 1998, 34, 378.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF02290729

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Published

1998-03-25

Issue

No. 3 (1998)

Section

Original Papers