Reactions of polyhalogenopyridines. 15. Reaction of isomeric tetrachlorocyanopyridines and pentachloropyridine with potassium isopropyltrithiocarbonate

Authors

  • А. М. Сипягин Chernogolovka Institute of Chemical Physics, Chernogolovka 142432
  • B. B. Колчанов Chernogolovka Institute of Chemical Physics, Chernogolovka 142432
  • 3. Г. Алиев Chernogolovka Institute of Chemical Physics, Chernogolovka 142432
  • Н. K. Караханова M. V. Lomonosov Moscow State University, Moscow 119899
  • А. T. Лебедев M. V. Lomonosov Moscow State University, Moscow 119899

Abstract

The reaction of isomeric tetrachlorocyanopyridines and pentachloropyridine with potassium isopropyltrithiocarbonate was investigated. It was found that the structure and composition of the reaction products depend both on the initial polychloropyridines and on the solvent in which the process is carried out. The intramolecular transformations of the isopropyltrithiocarbonate derivatives of tetrachloro-2-cyanopyridine in acetonitrile solution lead to 1,3-dithiolo[4,5-c]pyridines. In other cases heterocyclization was not observed. If the reactions were conducted in ethanol (except with tetrachloro-3-cyanopyridine) thioalkylation of the pyridine ring occurred.

How to Cite
Sipyagin, A. M.; Kolchanov, V. V.; Aliev, Z. G.; Karakhanova, N. K.; Lebedev, A. T. Chem. Heterocycl. Compd. 1998, 34, 297. [Khim. Geterotsikl. Soedin. 1998, 34, 330.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF02290720

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Published

1998-03-25

Issue

No. 3 (1998)

Section

Original Papers