Formation of derivatives of benzofuran, indole, and cinnoline in the reaction of 7-(N-morpholinyl)-7-methyl-8a-hydroxy-4,5,8,8a-tetrahydro-7H-pyrrolo[3,2-<i>e</i>]-2,1,3-benzoxadiazole 6-oxide with nucleophilic reagents

Authors

  • B. А. Самсонов Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk 630090
  • Л. Б. Володарский Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk 630090

Abstract

7-(N-Morpholinyl)-7-methyl-8a-hydroxy-4,5,8,8a-tetrahydro-7H-pyrrolo[3,2-e]-2,1,3-benzoxadiazole 6-oxide behaves as the synthetic equivalent of a 1,4-dicarbonyl compound in reactions with amines, dioxime, and hydrazine to give derivatives of benzofuran, indole, 1,4-dioxime, and pyridazine. This compound also undergoes reactions characteristic for nitrones, adding water and a hydride ion.

How to Cite
Samsonov, V. A.; Volodarskii, L. B. Chem. Heterocycl. Compd. 1998, 34, 271. [Khim. Geterotsikl. Soedin. 1998, 34, 303.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF02290715

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Published

1998-03-25

Issue

No. 3 (1998)

Section

Original Papers