Saturated nitrogen-containing heterocycles. 17. Synthesis and catalytic hydrogenation of 9,10-substituted decahydroacridines (mechanism of hydroamination of β-cycloketols)

Authors

  • Т. Г. Николаева N. G. Chernyshevskii Saratov State University, Saratov 410600
  • И. C. Поддубный N. G. Chernyshevskii Saratov State University, Saratov 410600
  • А. П. Кривенько N. G. Chernyshevskii Saratov State University, Saratov 410600

Abstract

The synthesis of 9,10-substituted decahydroacridines was carried out, and their catalytic hydrogenation was studied. The participation of these compounds as intermediates in the formation of perhydroacridines in the reaction of catalytic hydroamination of 8-R-2-hydroxy-13-oxotricyclo[7.3.1.02.7]tridecanes was established. The 1H and 13C NMR spectra of the synthesized compounds are given.

How to Cite
Nikolaeva, T. G.; Poddubnyi, I. S.; Kriven'ko, A. P. Chem. Heterocycl. Compd. 1995, 31, 823. [Khim. Geterotsikl. Soedin. 1995, 945.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01170743

Published

1995-07-25

Issue

Section

Original Papers